Expert Advice

Understanding Corrosion: Causes and Prevention Strategies

Written by Stephen Watt | Feb 17, 2025 6:19:55 AM

Corrosion is a natural process that gradually deteriorates materials, particularly metals, due to chemical reactions with their environment. Left unchecked, corrosion can lead to structural failures, safety risks, and costly repairs. Understanding what causes corrosion and how to prevent it is essential for industries ranging from construction and manufacturing to marine and aerospace engineering.

What Is Corrosion?

Corrosion is a chemical or electrochemical reaction between a metal and its environment that leads to its deterioration. The most common form is rust, which occurs when iron or steel reacts with oxygen and moisture, forming iron oxide. However, corrosion can affect a wide range of materials and take many forms, from surface discolouration to deep structural damage.

Common Causes of Corrosion

Several factors contribute to corrosion, and in many cases, multiple causes interact to accelerate metal degradation.

1. Environmental Exposure

The environment plays a major role in corrosion rates. Some of the most common environmental contributors include:

  • Moisture and Humidity: Water is a primary factor in corrosion. When metals are exposed to moisture, oxidation speeds up, leading to rust and pitting.
  • Salt and Marine Environments: Coastal and offshore structures are highly vulnerable to corrosion because saltwater is a strong electrolyte, accelerating the corrosion process.
  • Pollutants and Industrial Chemicals: Acidic gases such as sulphur dioxide and nitrogen oxides, found in polluted air, react with moisture to create acidic conditions that corrode metals.

2. Electrochemical Reactions

Corrosion is often driven by electrochemical processes, particularly when different metals come into contact in the presence of an electrolyte (such as water or saltwater). This leads to galvanic corrosion, where the less noble metal corrodes faster. Common examples include:

  • Corrosion in boats and ship hulls due to contact between steel and aluminium
  • Pipeline degradation where different metal components interact underground
  • Deterioration of fasteners and bolts in mixed-metal assemblies

3. Temperature Variations

Extreme temperatures and fluctuating thermal conditions can accelerate corrosion by expanding and contracting materials, leading to stress fractures and micro-cracks. High temperatures also speed up chemical reactions, making metals more susceptible to oxidation.

4. Microbial Corrosion

Some types of bacteria can produce acidic or corrosive by-products that accelerate metal degradation. This is known as microbiologically influenced corrosion (MIC) and is especially problematic in water treatment plants, oil pipelines, and underground infrastructure. Bacteria that produce hydrogen sulphide, for example, can cause severe corrosion in steel structures.

Best Practices to Prevent Corrosion

Although corrosion is a natural process, there are several ways to slow it down or prevent it altogether. Proper prevention methods can extend the lifespan of equipment, improve safety, and reduce maintenance costs.

1. Protective Coatings and Paints

Applying a protective coating creates a barrier between the metal and its environment, reducing exposure to moisture, oxygen, and chemicals. Common protective coatings include:

  • Paints and powder coatings for structural steel, machinery, and vehicles
  • Galvanisation (zinc coating) for corrosion protection in steel structures
  • Epoxy and polymer coatings used in marine and industrial applications

2. Cathodic Protection

Cathodic protection is an electrochemical technique used to prevent corrosion in pipelines, ships, and underground tanks. It works by using a sacrificial anode (a more reactive metal) that corrodes instead of the protected structure. There are two main types:

  • Sacrificial Anode Protection (SAP): Uses metals such as zinc, magnesium, or aluminium to attract corrosion away from the protected metal.
  • Impressed Current Cathodic Protection (ICCP): Uses an external power source to control corrosion more precisely.

3. Choosing Corrosion-Resistant Materials

The selection of materials can significantly impact corrosion resistance. Some metals and alloys naturally withstand corrosion better than others:

  • Stainless steel resists rust due to its chromium content.
  • Aluminium alloys develop a protective oxide layer that prevents further corrosion.
  • Weathering steel (Corten steel) forms a stable rust-like appearance that protects against deeper corrosion.

4. Environmental Controls

Minimising exposure to corrosive environments can slow down the corrosion process. Some effective measures include:

  • Reducing humidity using dehumidifiers and ventilation systems
  • Applying water-repellent coatings on outdoor structures
  • Sealing joints and crevices to prevent moisture accumulation
  • Avoiding direct contact between dissimilar metals to prevent galvanic corrosion

5. Regular Inspections and Maintenance

Routine inspections can help identify early signs of corrosion before they cause major damage. A proactive maintenance strategy should include:

  • Visual inspections for rust, pitting, and surface damage
  • Ultrasonic and infrared testing to detect corrosion in hidden areas
  • Cleaning and reapplying protective coatings as needed
  • Replacing worn or corroded parts before they compromise structural integrity

6. Using Corrosion Inhibitors

Corrosion inhibitors are chemicals that slow down the corrosion process by forming a protective layer on the metal’s surface. These are commonly used in:

  • Cooling systems to prevent rust in water pipes
  • Oil and gas pipelines to reduce metal degradation
  • Industrial equipment to extend the life of machinery exposed to corrosive substances

7. Corrosion Testing and Monitoring

Corrosion testing is essential for identifying potential issues early and ensuring preventive measures are effective. Using specialised corrosion testers, businesses can monitor corrosion rates, assess the condition of protective coatings, and evaluate material durability under various environmental conditions. Regular testing helps detect problems before they cause significant damage, allowing for timely interventions that extend the lifespan of equipment and infrastructure.

Conclusion

Corrosion is an unavoidable challenge in many industries, but with the right prevention strategies, its impact can be minimised. Protective coatings, cathodic protection, material selection, and regular maintenance are all effective ways to combat corrosion. By taking a proactive approach, businesses can reduce costs, improve safety, and extend the lifespan of critical infrastructure.